Transport of Pollutants by the Sea Breeze in São Paulo under the South Atlantic High

Abstract

The land-sea breeze circulation is important for the Metropolitan Region of São Paulo (MRSP), influencing predominant wind direction during the night and day, and so, the transport of pollution in the local scale. In the summer of 2014, there were 43 exceedances of the state air quality by ozone, when the South Atlantic Subtropical High strengthened over southeast Brazil. We aimed to study how the land-sea breeze circulation influenced the transport of the pollutants CO, NO, NO2 and O3 in the study area using the WRF/Chem model in the period 28/01-01/02/2014. Two scenarios were considered: CTRL – vehicular emissions based on current emission inventories and SENS – removing 75% of emissions in the MRSP. Results were analysed through maps with the spatial distribution of pollutants in the domain and showed the importance of the land-sea breeze circulation for the transport of pollution. Analysis of the divergence field proved useful for identifying the sea breeze front. Higher O3 concentrations were simulated in the prefrontal convergence line, due to stagnation and accumulation of pollutants brought by the passage of the sea breeze over polluted areas, resulting in the transport of ozone and other pollutants to distant areas northwest during the afternoon and evening. There was also transport of pollutants to the south in the early morning caused by the land breeze. Upward air motion due to the convergence in the prefrontal region caused vertical transport of ozone during the afternoon.