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Acidic and cesium salts of polyoxometalates with and without vanadium supported on MCM-41 as catalysts for oxidation of cyclohexane with H2O2

  • Trakarnpruk W
  • Jatupisarnpong J
Applied Petrochemical Research (2013) 3(1-2) 9-15
DOI: 10.1007/s13203-012-0023-5
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Abstract

Acidic and cesium salts of polyoxometalate (POM) with and without vanadium supported on MCM-41 were synthesized and their catalytic activities were investigated in the oxidation of cyclohexane with H2O2 under solvent-free condition. The products are cyclohexanol and cyclohexanone. The catalytic activity order is: CsVPOM/MCM > HVPOM/MCM > CsPOM/MCM {\textasciitilde} HPOM/MCM > CsVPOM > CsPOM catalysts. High conversion and selectivity to cyclohexanone over the supported catalysts are due to redox property and high surface area. These heterogeneous catalysts can be reused.

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APA

Trakarnpruk, W., & Jatupisarnpong, J. (2013). Acidic and cesium salts of polyoxometalates with and without vanadium supported on MCM-41 as catalysts for oxidation of cyclohexane with H2O2. Applied Petrochemical Research, 3(1–2), 9–15. https://doi.org/10.1007/s13203-012-0023-5

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