Gold-catalyzed dealkoxylative carbocyclization/[3+3] annulation cascade of acetal-allene or ketal-allene substrates

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Abstract

(Chemical Equatation Reprentation) Rapid construction: We report the first successful implementation of a catalytic tandem carbocyclization/annulation cascade reaction (e.g., see scheme) using acetal-allene or ketal-aliene substrates through a dealkoxylative mode. This gold catalysis enables a rapid stereocontrolled construction of oxacyclic or carbocyclic frameworks. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA,.

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Teng, T. M., Lin, M. S., Vasu, D., Bhunia, S., Liu, T. A., & Liu, R. S. (2010). Gold-catalyzed dealkoxylative carbocyclization/[3+3] annulation cascade of acetal-allene or ketal-allene substrates. Chemistry - A European Journal, 16(16), 4744–4748. https://doi.org/10.1002/chem.201000041

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