Abstract
Trimethylsilyl-substituted organometallic compounds, (CH2)3SiCHMR, have been demonstrated to be effective intermediates in the conversion of carbonyl compounds to the corresponding olefins, >C=CHR. These conversions, which involve the formation and decomposition of ⪫ SiCHRC(OM)< compounds, appear to be closely related to the classical methods of preparing olefins from reactions of phosphorus-substituted carbanions with aldehydes and ketones. © 1968, American Chemical Society. All rights reserved.
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CITATION STYLE
Peterson, D. J. (1968). A Carbonyl Olefination Reaction Using Silyl-Substituted Organometallic Compounds. Journal of Organic Chemistry, 33(2), 780–784. https://doi.org/10.1021/jo01266a061
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