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Catalytic asymmetric α-amination of α-branched ketones via enol catalysis

Synlett (2015) 26(10) 1413-1416
DOI: 10.1055/s-0034-1380680
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Abstract

We report a highly enantioselective α-amination of α-branched ketones catalyzed by a chiral phosphoric acid employing azodicarboxylates as reagents. The desired products were obtained in good to excellent yields and enantioselectivities.

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Shevchenko, G. A., Pupo, G., & List, B. (2015). Catalytic asymmetric α-amination of α-branched ketones via enol catalysis. Synlett, 26(10), 1413–1416. https://doi.org/10.1055/s-0034-1380680

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