Abstract
The ratio of the intensity of Tb3+fluorescence at 543 nm because of an electric dipole transition (5D4-7F5) relative to that at 437 nm due to a magnetic dipole transition (5D3-7F4) was determined to be proportional to the amount of metastable CaAl2Si2O8crystals precipitated in CaO-Al2O3-SiO2glass. The present results indicate that Tb3+luminescence can be used as a probe to evaluate the crystallization of glass.
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CITATION STYLE
Machida, S., Yamaguchi, T., Emori, N., Katsumata, K. I., Maeda, K., & Yasumori, A. (2022). Assessment of the Crystallization Process of CaO-Al2O3-SiO2Glass Probed with Tb3+Luminescence. Inorganic Chemistry, 61(29), 11478–11483. https://doi.org/10.1021/acs.inorgchem.2c01950
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