Upgrading the Properties of the Crude Oil-Water System for EOR with Simultaneous Effects of a Homologous Series of NanoGemini Surface-Active Ionic Liquids, Electrolytes, and pH

Abstract

This study investigated the simultaneous effects of electrolytes, NaCl and MgCl2electrolytes, individually and as a mixture, and pH on a homologous series of imidazolium nano-Gemini surface-active ionic liquids (GSAILs), [C4im-Cm-imC4][Br2], where m = 2, 4, and 6. These can improve the properties of the crude oil-water system and consequently enhance the oil recovery. The results precisely revealed that interfacial tension (IFT) and critical micelle concentration were initially decreased with electrolyte concentration up to 55.7 and 58.6%, respectively, in comparison to the salt-free condition, followed by a slight increase. Moreover, adjusting the pH can provide a further improvement so that 79.2% IFT reduction is attained at pH 9.5 compared to that at the natural pH and that GSAILs show high stability in the pH range of 2.5-9.5. Meanwhile, aqueous solutions of crude oil and electrolyte presented 1 day emulsification indices within 43-53%, followed by minor changes after 1 week. Interestingly, the emulsification index of 77.1% was attained at pH 9.5. Surface wettability was also favorably altered from oil-wet to water-wet with the nanoGSAILs. The findings of this study help gain a better understanding of the effects of nanosurface active materials to improve oil extraction under reservoir conditions.