Tunable photochemical/redox properties of (phenylthio)ncorannulenes: Application to a photovoltaic device

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Abstract

The additive substituent effect of phenylmercapto derivatives of corannulene are investigated by spectroscopic, electrochemical, and computational techniques. The per-substituted phenylmercaptocorannulene is incorporated as a replacement for [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a photovoltaic device.

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Steinauer, A., Butterfield, A. M., Linden, A., Molina-Ontario, A., Buck, D. C., Cotta, R. W., … Siegel, J. S. (2016). Tunable photochemical/redox properties of (phenylthio)ncorannulenes: Application to a photovoltaic device. Journal of the Brazilian Chemical Society, 27(10), 1866–1871. https://doi.org/10.5935/0103-5053.20160072

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