The hydrodynamical equations and the notion of a frequency dependent complex specific heat near the critical point of binary liquids are used to obtain an expression for the low-frequency bulk viscosity. In this way the interrelations between different theoretical models, treating the critical sound attenuation from either a specific heat or a bulk viscosity approach, are made evident. The general structure of the bulk viscosity relation agrees with that of Onuki [Phys. Rev. E 55, 403 (1997)] but a universal number emerges only if a normalization to the critical point value is done. © 2009 American Institute of Physics.
CITATION STYLE
Bhattacharjee, J. K., Iwanowski, I., & Kaatze, U. (2009). Bulk viscosity universality and scaling function near the binary liquid consolute point. Journal of Chemical Physics, 131(17). https://doi.org/10.1063/1.3258279
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