Stereoselective C-glycosylation of furanosyl halides with arylzinc reagents

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Abstract

Were are reporting a highly diastereoselective, transition-metal-free approach of C-aryl glycosides in the pyranoside and furanoside series by the direct coupling of glycosyl halides with diarylzinc reagents in a toluene/di-n-butyl ether solvent mixture. © 2014 IUPAC.

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Lemaire, S., Xolin, A., Gozlan, C., & Farina, V. (2014). Stereoselective C-glycosylation of furanosyl halides with arylzinc reagents. In Pure and Applied Chemistry (Vol. 86, pp. 329–333). IUPAC Secretariat. https://doi.org/10.1515/pac-2013-1029

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