Colorimetric detection of hydrogen peroxide by dioxido-vanadium(V) complex containing hydrazone ligand: Synthesis and crystal structure

Abstract

Dioxido-vanadium(V) complex has been synthesized in good yield, the complex was characterized by IR, UV–visible and1 H NMR spectroscopy. Single crystal X-ray crystallography techniques were used to assign the structure of the complex. Complex crystallized with monoclinic P21/c space group with cell parameters a (Å) = 39.516(5), b (Å) = 6.2571(11), c (Å) = 17.424(2), α (°) = 90, β (°) = 102.668(12) and γ (°) = 90. The hydrazone ligand is coordinate to metal ion in tridentate fashion through –ONO– donor atoms forming a distorted square pyramidal geometry around the metal ion.