Abstract
Arenes can be chlorinated, brominated, and iodinated in the presence of CeO2 nanoparticles under aerobic conditions. In a biomimetic approach, active electrophilic halogen species are generated from either organic or inorganic halogen compounds and are trapped by arenes. This C-H transformation can be applied to the synthesis of naturally occurring products. © 2012 American Chemical Society.
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Leyva-Pérez, A., Cómbita-Merchán, D., Cabrero-Antonino, J. R., Al-Resayes, S. I., & Corma, A. (2013). Oxyhalogenation of activated arenes with nanocrystalline ceria. ACS Catalysis, 3(2), 250–258. https://doi.org/10.1021/cs300644s
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