Boson-peak vibrational modes in glasses feature hybridized phononic and quasilocalized excitations

Abstract

A hallmark of structural glasses and other disordered solids is the emergence of excess low-frequency vibrations on top of the Debye spectrum DDebye(ω) of phonons (ω denotes the vibrational frequency), which exist in any solid whose Hamiltonian is translationally invariant. These excess vibrations—a signature of which is a THz peak in the reduced density of states D(ω)/DDebye(ω), known as the boson peak—have resisted a complete theoretical understanding for decades. Here, we provide direct numerical evidence that vibrations near the boson peak consist of hybridizations of phonons with many quasilocalized excitations; the latter have recently been shown to generically populate the low-frequency tail of the vibrational spectra of structural glasses quenched from a melt and of disordered crystals. Our results suggest that quasilocalized excitations exist up to and in the vicinity of the boson-peak frequency and, hence, constitute the fundamental building blocks of the excess vibrational modes in glasses.