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A 2-Aza-3,4-Diphospha-1-Bora-Butadiene

Zeitschrift fur Anorganische und Allgemeine Chemie (2022) 648(21)
DOI: 10.1002/zaac.202200174
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Abstract

The reaction of a lithiated supermesityl-substituted amino-diphosphene with boron trichloride yielded a formal 2-aza-3,4-diphospha-1-bora-heterobutadiene after LiCl elimination. X-ray structure and bonding analyses revealed a planar trans-bent B−N-P−P framework with short B−N and P−P bond lengths in accord with the description as a heterobutadiene derivative.

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Rothe, J., Bresien, J., Reiß, F., Villinger, A., Beweries, T., & Schulz, A. (2022). A 2-Aza-3,4-Diphospha-1-Bora-Butadiene. Zeitschrift Fur Anorganische Und Allgemeine Chemie, 648(21). https://doi.org/10.1002/zaac.202200174

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