Fabrication and Composition of MA1-yFAySnI3-xBrx Thin Films for Lead-Free Perovskite Solar Cells

Abstract

Perovskite solar cells have gained significant attention in recent years due to their lightweight nature, flexibility, and ability to generate power even in weak-light conditions. Despite these advantages, the current mainstream perovskite solar cells contain lead, raising concerns about their environmental and human health effects. Tin is expected to be a substitutional element for lead; however, tin-based perovskite solar cells currently have low power conversion efficiency. Altering the composition of the perovskite is crucial for enhancing its performance. In this study, perovskite solar cells with mixed MA/FA and I/Br components were designed and fabricated based on the calculation of the tolerance factor. The crystallinity and band gap of perovskite thin films were manipulated by changing the compositions of anions and cations. A suitable composition ratio for perovskite solar cells was proposed and discussed.