Abstract
Magnesium bromide radicals have to be prepared as high-temperature molecules and trapped as a metastable solution because a seemingly simple reduction of donor-free Grignard compounds failed. However, the essential role of magnesium(I) species during the formation of Grignard compounds could be demonstrated experimentally. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Kruczyński, T., Pushkarevsky, N., Henke, P., Köppe, R., Baum, E., Konchenko, S., … Schnöckel, H. (2012). Hunting for the magnesium(I) species: Formation, structure, and reactivity of some donor-free Grignard compounds. Angewandte Chemie - International Edition, 51(36), 9025–9029. https://doi.org/10.1002/anie.201204997
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