Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production

  • Dolgykh L
  • Stolyarchuk I
  • Staraya L
  • et al.
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Abstract

MnO, Mn 2 O 3 , Fe 2 O 3 and Fe 3 O 4 are catalytically active for the steam reforming of ethanol. The main reaction products were acetaldehyde, acetone, CO 2 and H 2 in the temperature range of 300–550°C. At low temperatures, high selectivity for acetone (up to 75%) was observed for MnO. Based on the study results, the relation between product selectivity of the oxide catalysts and their acid–base/redox properties balance is suggested. The selectivity for hydrogen was about 80% for Fe 2 O 3 at 550°C with 100% ethanol conversion.

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Dolgykh, L. Yu., Stolyarchuk, I. L., Staraya, L. A., Vasylenko, I. V., Pyatnitsky, Y. I., & Strizhak, P. E. (2015). Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production. Adsorption Science & Technology, 33(6–8), 715–721. https://doi.org/10.1260/0263-6174.33.6-8.715

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