The Influence of Sulfoxides and Sulfones on the Temperature of Maximum Density of Water

  • Macdonald D
  • Smith M
  • Hyne J
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Abstract

The influence of dimethyl sulfoxide (DMSO), diethyl sulfoxide (DESO), tetramethylene sulfoxide (TMSO), and tetramethylene sulfone (TMSO 2 ) on the temperature of maximum density of water bas been investigated. It is concluded that in dilute solution DESO stabilizes the characteristic three-dimensional structure of water. The other solutes, however, destabilize the structure of water over the entire concentration range studied (0–1.3 × 10 −2 mole fraction solute).

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Macdonald, D. D., Smith, M. D., & Hyne, J. B. (1971). The Influence of Sulfoxides and Sulfones on the Temperature of Maximum Density of Water. Canadian Journal of Chemistry, 49(17), 2817–2821. https://doi.org/10.1139/v71-469

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