Connecting mononuclear dysprosium single-molecule magnets to form dinuclear complexes via in situ ligand oxidation

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Abstract

A Dy2 complex, exhibiting SMM behaviour, and its Y analogue were prepared via in situ oxidation of Py2TTA, a pincer type ligand, followed by dimerisation. This unique metal complexation and subsequent dimerization were followed by solution NMR studies.

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Yutronkie, N. J., Kühne, I. A., Korobkov, I., Brusso, J. L., & Murugesu, M. (2016). Connecting mononuclear dysprosium single-molecule magnets to form dinuclear complexes via in situ ligand oxidation. Chemical Communications, 52(4), 677–680. https://doi.org/10.1039/c5cc07629c

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