Assessment of the sorption capacity and regeneration of carbon dioxide sorbents using thermogravimetric methods

Abstract

Adsorption methods using solid sorbents are an alternative to the absorption technology in the processes of purification gases from carbon dioxide. There is a need to rapidly assess the suitability of sorbents for use it in PSA, TSA, or VPSA installations. Important parameters which determine the quality of the sorbent are the sorption capacity of sorbent, selectivity to CO 2 and the possibility of regeneration. This paper presents the results of sorption/desorption of CO 2 study on the impregnated porous materials using thermogravimetric methods. Thermogravimetry allows for rapid assessment of sorption capacity and regeneration of the sorbents. Specially selected temperature program allowed to determine the sorption capacity of sorbents depending on the concentration of CO 2 in the gas mixture and temperature. Degree of sorbent purification was determined in desorption process. © 2013 The Author(s).