Tris-Co(II)-H2O2 System-Mediated Durative Hydroxyl Radical Generation for Efficient Anionic Azo Dye Degradation by Integrating Electrostatic Attraction

Abstract

The development of simple Fenton/Fenton-like systems with durative hydroxyl radical (•OH) generation characteristics is significant to rapid organic pollutant degradation and cost-effective water treatment. In this study, a tris(hydroxymethyl)aminomethane (Tris)-incorporated Co(II)-H2O2 Fenton-like system has been successfully constructed for efficient Sunset Yellow (SY, a typical anionic azo dye) degradation under alkaline conditions. The mechanism of the enhanced degradation consists of two parts: first, the Tris-Co(II) complex triggers the durative generation of highly oxidized hydroxyl radicals; second, electrostatic attraction between SY and the Tris-Co(II) complex shortens the radical-SY interaction time and facilitates the degradation of SY. With the introduction of Tris to this proposed system, the decolorization rate of SY can be increased from 37.0 to 98.0% after 50 min and efficient SY degradation with a high total organic carbon removal efficiency (>59.0%) is achieved under a wide initial pH from 8.7 to 12.0. Moreover, the universality of the designed system for anionic azo dye degradation is verified with reactive red and congo red.