Abstract
Hyperbranched polymethacrylates were synthesized by green-light-induced atom transfer radical polymerization (ATRP) under biologically relevant conditions in the open air. Sodium 2-bromoacrylate (SBA) was prepared in situ from commercially available 2-bromoacrylic acid and used as a water-soluble inibramer to induce branching during the copolymerization of methacrylate monomers. As a result, well-defined branched polymethacrylates were obtained in less than 30 min with predetermined molecular weights (36 000
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Kapil, K., Szczepaniak, G., Martinez, M. R., Murata, H., Jazani, A. M., Jeong, J., … Matyjaszewski, K. (2023). Visible-Light-Mediated Controlled Radical Branching Polymerization in Water. Angewandte Chemie - International Edition, 62(10). https://doi.org/10.1002/anie.202217658
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