Anomaly and geochemistry of rare earth elements and yttrium in the late Permian coal from the Moxinpo mine, Chongqing, southwestern China

Abstract

The rare earth elements and yttrium (REY) of the K2 coal from the Moxinpo mine, Chongqing, were determined using inductively coupled plasma mass spectrometry (ICP-MS). The results show that REY are enriched in the K2 coal, with the average content up to 462 μg/g, much higher than average values of most coals in the world. The REY distribution patterns indicate that the light REY is enriched and show a well-pronounced Eu minimum. The fractionation of individual light-REY is higher than that of the heavy-REY. The REY distribution through the K2 coal seam shows that the top and bottom portion of the coal seam have a lower content of REY than the middle portion. Goyazite and rhabdophane were identified with a scanning electron microscope equipped with an energy-dispersed X-ray spectrometer (SEM-EDX). The REY distributions through the coal seam, SEM-EDX data and the correlation analysis between ash yields and the concentrations have revealed that the REY mainly occurs in the organic matter. The K2 coal is a potential rare-metal resource due to its high REY contents, and the coal ash could be regarded as a new and promising raw material for recovery of REY as a by-product.