Abstract
A highly gas permeable polymer with exceptional size selectivity is prepared by fusing triptycene units together via a polymerization reaction involving Tröger's base formation. The extreme rigidity of this polymer of intrinsic microporosity (PIM-Trip-TB) facilitates gas permeability data that lie well above the benchmark 2008 Robeson upper bounds for the important O 2/N2 and H2/N2 gas pairs. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Carta, M., Croad, M., Malpass-Evans, R., Jansen, J. C., Bernardo, P., Clarizia, G., … McKeown, N. B. (2014). Triptycene induced enhancement of membrane gas selectivity for microporous Tröger’s base polymers. Advanced Materials, 26(21), 3526–3531. https://doi.org/10.1002/adma.201305783
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