Journal Article

Suzuki-Miyaura Csp2-Csp2Cross-Couplings Employing Nickel(II) Pincer Precatalysts: Mechanistic Investigations

Organometallics (2021) 40(14) 2305-2310
DOI: 10.1021/acs.organomet.1c00033
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Abstract

This study investigates the mechanism of Suzuki-Miyaura Csp2-Csp2cross-couplings facilitated by PCP-type nickel(II) pincer complexes. By employing a combination of standard experimental and theoretical methods, it is proposed that a nickel(I)/(III) cycle is involved in this reaction and single-electron pathways likely operate in this transformation.

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APA

Ho, C. C., Olding, A., Fuller, R. O., Canty, A. J., Lucas, N. T., & Bissember, A. C. (2021). Suzuki-Miyaura Csp2-Csp2Cross-Couplings Employing Nickel(II) Pincer Precatalysts: Mechanistic Investigations. Organometallics, 40(14), 2305–2310. https://doi.org/10.1021/acs.organomet.1c00033

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