Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67

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Abstract

The encapsulation of polyoxometalates within the large pores of the Zr(iv) biphenyldicarboxylate UiO-67 metal-organic framework has been achieved, for the first time, by direct solvothermal synthesis. The resulting POM@UiO-67 composite materials were fully characterized by XRPD, IR, MAS NMR, N2 porosimetry measurements and cyclic voltammetry.

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Salomon, W., Roch-Marchal, C., Mialane, P., Rouschmeyer, P., Serre, C., Haouas, M., … Dolbecq, A. (2015). Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67. Chemical Communications, 51(14), 2972–2975. https://doi.org/10.1039/c4cc09986a

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