New colours for carotenoids - synthesis of pyran polyenes

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Abstract

A new type of carotenoid has been synthesized with a 2Hpyran ring placed in the polyene chain. This compound was successively elongated by Wittig reactions. The pyran-carotenoids obtained show a significant increased A max compared with carotenoids lacking the pyran ring. A further remarkable bathochromic shift was observed upon protonation to pyranium-carotenoids. The pyranium ring is the distinctive feature of anthocyanidin dyes and has now become an internal part of carotenoids. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

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Øpstad, C. L., Sliwka, H. R., & Partali, V. (2010). New colours for carotenoids - synthesis of pyran polyenes. European Journal of Organic Chemistry, (3), 435–439. https://doi.org/10.1002/ejoc.200901093

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