Quinoline-: Para -quinones and metals: Coordination-assisted formation of quinoline- ortho -quinones

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Abstract

The reaction of the para-quinone 6,7-dichloroquinoline-5,8-dione with various transition metal dimers led to the unexpected formation of quinoline-ortho-quinone metal complexes. Systematic variation of the reaction conditions helped identify the solvent as the source of the carbonyl oxygen.

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Kubanik, M., Lam, N. Y. S., Holtkamp, H. U., Söhnel, T., Anderson, R. F., Jamieson, S. M. F., & Hartinger, C. G. (2018). Quinoline-: Para -quinones and metals: Coordination-assisted formation of quinoline- ortho -quinones. Chemical Communications, 54(8), 992–995. https://doi.org/10.1039/c7cc09478g

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