Reconstructing atmospheric H2 over the past century from bi-polar firn air records

Abstract

Historical atmospheric H2 levels were reconstructed using firn air measurements from two sites in Greenland (NEEM and Summit) and two sites in Antarctica (South Pole and Megadunes). A joint reconstruction based on the two Antarctic sites yields H2 levels monotonically increasing from about 330gppb in 1900 to 550gppb in the late 1990s, leveling off thereafter. These results are similar to individual reconstructions published previously (Patterson et al., 2020, 2021). Interpretation of the Greenland firn air measurements is complicated by challenges in modeling enrichment induced by pore close-off at these sites. We used observations of neon enrichment at NEEM and Summit to tune the parameterization of enrichment induced by pore close-off in our firn air model. The joint reconstruction from the Greenland data shows H2 levels rising 30g% between 1950 and the late 1980s, reaching a maximum of 530gppb. After 1990, reconstructed atmospheric H2 levels over Greenland are roughly constant, with a small decline of 3g% over the next 25 years. The reconstruction shows good agreement with the available flask measurements of H2 at high northern latitudes.