Investigating the Effect of Bi2MoO6/g-C3N4 Ratio on Photocatalytic Degradation of Sulfadiazine under Visible Light

Abstract

In this study, a series of Bi2MoO6/g-C3N4 composites were prepared through a wet-impregnation method, and their photocatalytic properties were investigated for the degradation of sulfadiazine (SDZ) under visible light irradiation. Physical and chemical characterizations were carried out using X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), photoluminescence spectroscopy (PL), UV-vis diffuse reflectance spectra (UV-vis), and electrochemical impedance spectra (EIS). Compared to pure g-C3N4, the introduction of Bi2MoO6 significantly enhanced the visible light responsive photocatalytic activity, with the 1:32 Bi2MoO6/g-C3N4 composite exhibiting the highest photodegradation efficiency towards SDZ under visible light irradiation with a photocatalytic efficiency of 93.88% after 120 min of visible light irradiation. The improved photocatalytic activity can be attributed to the formation of a heterojunction between Bi2MoO6 and g-C3N4, which promotes the transfer of photogenerated electron-hole pairs, thereby elevating its photocatalytic activity. The results suggest that Bi2MoO6/g-C3N4 composites have potential application for the degradation of sulfonamides in aquatic environments.