Facial One-Pot Synthesis, Characterization, and Photocatalytic Performance of Porous Ceria

Abstract

A facial one-step synthesis procedure was applied to prepare porous sponge-like ceria (CeO2). The synthesis was performed by mixing cerium nitrate with citric acid, followed by thermal treatment. The produced solid material was characterized by several techniques, such as XRD, SEM, N2 sorption measurement, DR-UV-vis, and Raman spectroscopy. The characterization data showed that the nanoparticles of the porous ceria were formed with a three-dimensional pore system. Moreover, the measured surface area of the porous sample was eight times higher than the commercially available ceria. The photocatalytic performance of the porous ceria was investigated in two different applications under visible light illumination. The first was the decolorization of a methyl green aqueous solution, while the second was the photocatalytic elimination of a gaseous mixture consisting of five short-chain hydrocarbons (C1–C3). The obtained results showed that the photocatalytic activity of porous ceria was higher than that of the commercial sample. Finally, the recycling of porous ceria showed low deactivation (less than 9%) after four consecutive runs.