A lutetium cyclopentadienyl-phosphazene constrained geometry complex (CGC): First isolobal analogues of group 4 cyclopentadienyl-silylamido CGC systems

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Abstract

C5Me4HPMe2 reacts with 1-adamantyl azide to form the first example of a new family of cyclopentadienylideneaminophosphorane ligands (1). Metallation of 1 with Lu(CH2SiMe3)3-(THF)2 leads to the first cyclopentadienyl-phosphazene CGC 2, isolobal to known group 4 cyclopentadienyl-silylamido CGC systems. © Wiley-VCH Verlag GmbH & Co. KGaA, 2005.

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Rufanov, K. A., Petrov, A. R., Kotov, V. V., Laquai, F., & Sundermeyer, J. (2005). A lutetium cyclopentadienyl-phosphazene constrained geometry complex (CGC): First isolobal analogues of group 4 cyclopentadienyl-silylamido CGC systems. European Journal of Inorganic Chemistry, (19), 3805–3807. https://doi.org/10.1002/ejic.200500529

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