Determination of kinetics in gas-liquid reaction systems. An overview

Abstract

The aim of this paper is to present a brief review of the determination methods of reaction kinetics in gas-liquid systems with a special emphasis on CO2 absorption in aqueous alkanolamine solutions. Both homogenous and heterogeneous experimental techniques are described with the corresponding theoretical background needed for the interpretation of the results. The case of CO2 reaction in aqueous solutions of methyldiethanolamine is discussed as an illustrative example. It was demonstrated that various measurement techniques and methods of analyzing the experimental data can result in different expressions for the kinetic rate constants.