Enantiomer-discriminating sensing using optical cavities at exceptional points

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Abstract

We propose a method for the detection of the handedness of otherwise identical chiral molecules using the coupling to a high-Q cavity at an exceptional point. In particular, we show that the rates of spontaneous emission for left- or right-handed enantiomers interacting with the cavity mode can be strongly enhanced or suppressed. This provides a strong spectroscopic signature to distinguish enantiomers. The enantioselectivity is shown to be robust against perturbations that move the cavity mode away from the exceptional point.

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Khanbekyan, M., & Scheel, S. (2022). Enantiomer-discriminating sensing using optical cavities at exceptional points. Physical Review A, 105(5). https://doi.org/10.1103/PhysRevA.105.053711

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