Abstract
Superelectrophilic chemistry in the gas phase is driven by the high intrinsic reactivity of dications. The formation of new doubly charged products proceeds via highly internally excited intermediates. Conditions for the formation of the doubly charged intermediates and a "cooling principle" in the reactivity of dications are explained. The reactivity is demonstrated with several examples. © 2011 IUPAC.
Author supplied keywords
Cite
CITATION STYLE
APA
Roithová, J. (2011). Superelectrophilic chemistry in the gas phase. Pure and Applied Chemistry, 83(8), 1499–1506. https://doi.org/10.1351/PAC-CON-10-10-17
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
Already have an account? Sign in
Sign up for free