Asymptotically scale-invariant occupancy of phase space makes the entropy Sq extensive

Abstract

Phase space can be constructed for N equal and distinguishable subsystems that could be probabilistically either weakly correlated or strongly correlated. If they are locally correlated, we expect the Boltzmann-Gibbs entropy S BG ≡ -k ∑i In pi to be extensive, i.e., SBG(N) ∝ N for N → ∞. In particular, if they are independent, SBG is strictly additive, i.e., SBG(N) = NSBG(1), ∀N. However, if the subsystems are globally correlated, we expect, for a vast class of systems, the entropy Sq ≡ k[1 - ∑i piq]/(q - 1) (with S 1 = SBG) for some special value of q ≠ 1 to be the one which is extensive [i.e., Sq(N) ∝ N for N → ∞]. Another concept which is relevant is strict or asymptotic scale-freedom (or scale-invariance), defined as the situation for which all marginal probabilities of the N-system coincide or asymptotically approach (for N → ∞) the joint probabilities of the (N - 1)-system. If each subsystem is a binary one, scale-freedom is guaranteed by what we hereafter refer to as the Leibnitz rule, i.e., the sum of two successive joint probabilities of the N-system coincides or asymptotically approaches the corresponding joint probability of the (N - 1)-system. The kinds of interplay of these various concepts are illustrated in several examples. One of them justifies the title of this paper. We conjecture that these mechanisms are deeply related to the very frequent emergence, in natural and artificial complex systems, of scale-free structures and to their connections with nonextensive statistical mechanics. Summarizing, we have shown that, for asymptotically scale-invariant systems, it is Sq with q ≠ 1, and not SBG, the entropy which matches standard, clausius-like, prescriptions of classical thermodynamics. © 2005 by The National Academy of Sciences of the USA.