Corrosion properties of a Ti-15Mo/TiB composite produced by spark plasma sintering

Abstract

Corrosion properties of Ti-15Mo/TiB metal-matrix composite in the initial as-sintered condition and after multiaxial forging (MAF) at 700°C were studied in comparison with commercially pure (CP) Ti and Ti-15wt.% Mo alloy. All the specimens were produced by spark plasma sintering at 1400°C using corresponding powder mixtures. Both CP hcp Ti and bcc Ti-15Mo had microstructures with a grain (or colonies of lamellae) size of ∼20 μm. Microstructure of the as-sintered composites consisted of TiB whiskers heterogeneously distributed within the bcc Ti matrix. Intensive shortening of TiB whiskers occurred during the MAF. Hardness of Ti increased due to an addition of Mo; hardness of the composites increased further in comparison with Ti-15Mo. After MAF the hardness did not change noticeably. Corrosion tests conducted using the electrochemical method showed some improvement due to an addition of Mo and TiB reinforcements into the Ti matrix. MAF also increased corrosion properties, however the development of pitting corrosion at potentials E ≈4000 mV can be expected.