A low-cost, low-density, and corrosion resistant AlFeMnSi compositionally complex alloy

Abstract

A compositionally complex alloy was designed, consisting of equiatomic concentrations of four low-cost commodity elements (Al, Fe, Mn, and Si). The alloy was characterized using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The corrosion of the AlFeMnSi alloy, as evaluated using potentiodynamic polarization tests and electrochemical impedance spectroscopy in 0.6 M NaCl solution, was comparable with that of stainless steel (SS) 304L. Detailed X-ray photoelectron spectroscopy analysis was carried out, including the determination of high-resolution spectra and surface sputtering. In addition, scanning transmission electron microscopy was also used to study the surface film(s) developed after constant immersion. The AlFeMnSi alloy exhibited a unique form of ‘passivity’ that arises from the development of a silicon-rich surface film from dynamic incongruent dissolution.