Rheological properties and chemical analysis of nanoclay and carbon microfiber modified asphalt with Fourier transform infrared spectroscopy

Abstract

This work aims to improve the rutting and fatigue cracking resistance of asphalt binders using selected nano- or micro-sized materials and to shed light on the microstructure changes induced by such modification to asphalt binders. The four modifiers (Nanomer I.44P, carbon microfiber, non-modified nanoclay and polymer modified nanoclay) were added into the control asphalt binder (PG 58-34). The Superpave™ tests and Fourier transform infrared spectroscopy (FTIR) measurements were conducted for obtaining the complex shear modulus G and microstructure distribution of modified asphalt binders. Meanwhile, the short-term and long-term aging processes of asphalt binders are simulated by rolling thin film oven (RTFO) and pressure aging vessel (PAV) tests. From the dynamic shear rheometer (DSR) and FTIR tests results, the complex shear modulus G values of nano- or micro-materials (Nanomer I.44P, non-modified nanoclay and carbon microfiber) modified asphalt binders increase, and the performance of resistance to rutting is improved compared to the control asphalt binder. The addition of polymer modified nanoclay (PMN) into the control asphalt binder decreases the complex shear modulus, and enhances the resistance to fatigue cracking. Moreover, the addition of four modifiers into the control asphalt binder can delay and weaken the aging and oxidation effect. © 2012 Elsevier Ltd. All rights reserved.