Plasma Functionalization of Multi-Walled Carbon Nanotubes for Ammonia Gas Sensors

Abstract

The role of plasma functionalization of multi-walled carbon nanotubes (MWCNTs) for room-temperature ammonia gas sensors was investigated. Plasma functionalization of MWCNTs with maleic anhydride was carried out at various durations. The active material of the gas sensor was investigated by scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It was shown that the formation of functional groups on the surface of carbon nanotubes led to an increase in the ammonia sensor response by two to four times. The increase in functionalization duration induced the rise of O/C from 0.28 to 0.335, an increase in sensor resistance, and the distortion of the shape of the I-V curves.