Negative area compressibility in silver(i) tricyanomethanide

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Abstract

The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation. © 2014 Partner Organisations.

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Hodgson, S. A., Adamson, J., Hunt, S. J., Cliffe, M. J., Cairns, A. B., Thompson, A. L., … Goodwin, A. L. (2014). Negative area compressibility in silver(i) tricyanomethanide. Chemical Communications, 50(40), 5264–5266. https://doi.org/10.1039/c3cc47032f

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