Silicon-directed Norrish type I cleavage of β-trimethylsilyl cycloalkanones

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Abstract

The Me3Si group in β-trimethylsilyl cycloalkanones was able to direct the Norrish type I cleavage by providing regioselectivity in the C-1-C-2 bond cleavage and by increasing the quantum yield and the reaction rate.

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Hwu, J. R., Gilbert, B. A., Lin, L. C., & Liaw, B. R. (1990). Silicon-directed Norrish type I cleavage of β-trimethylsilyl cycloalkanones. Journal of the Chemical Society, Chemical Communications, (2), 161–163. https://doi.org/10.1039/C39900000161

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