Monitoring of ppm level humic acid in surface water using ZnO–chitosan nano-composite as fluorescence probe

Abstract

Surface water contains natural pollutants humic acid (HA) and fulvic acid at ppm level which form carcinogenic chloro-compounds during chlorination in water treatment plants. We report here synthesis of ZnO–chitosan (CS) nano-composites by simple hydrothermal technique and examined their application potential as fluorescent probe for monitoring ppm level HA. These ZnO–CS composites have been characterized by HRTEM, EDX, FTIR, AFM and Fluorescence Spectra. HRTEM images show the formation of ZnO–CS nano-composites of average diameter of 50–250 nm. Aqueous dispersions of these nano-composites show fluorescence emission at 395 nm when excited at 300 nm which is strongly quenched by ppm level HA indicating their possible use in monitoring ppm level HA present in surface water.