Abstract
(Figure Presented) Bowled over: A bowl-shaped {Mo51V 9} polyoxo metal ate anion (see picture) is produced in a hydrothermal synthesis by a redox self-assembly process. This new compound has different building blocks and linkages to previously reported polyoxometalates (see structure; N green, O red, Mo/V gray, threefold axis indicated by black triangle). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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Wang, S., Lin, X., Wan, Y., Yang, W., Zhang, S., Lu, C., & Zhuang, H. (2007). A large, bowl-shaped {Mo51V9} polyoxometalate. Angewandte Chemie - International Edition, 46(19), 3490–3493. https://doi.org/10.1002/anie.200700076
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