Rational approach to thermodynamic rrocesses and constitutive equations in isothermal and non-isothermal kinetics

Abstract

Isothermal and non-isothermal kinetics are classified according to the viewpoint of rational approach. The appropriate selection of basic quantities and constitutive equations is stressed. The extensive discussion recently focused to the meaning of the partial derivatives is reinvestigated and clarified considering the origin of following equation {Mathematical expression} where α is the extent of reaction, T and t are the temperature and time respectively, and f represents a function. The meaning of partial derivatives is demonstrated in details. The disagreement sometimes claimed between the data evaluated by means of isothermal and non-isothermal kinetics is also reviewed, but no fundamental differences are established. © 1973 Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest.