UiO-66-NH2 metal-organic framework supported palladium/Schiff-base complex as a highly efficient and robust catalyst for the Suzuki reaction

Abstract

The synthesis of C-C bonds is considered one of the most fundamental challenges in both organic chemistry and the chemical industry, as these bonds are essential for the preparation of high-value products. Therefore, it is crucial to develop efficient, cost-effective, and environmentally sustainable methods for C-C bond formation. In this context, herein, a novel Schiff-base/Pd-functionalized Zr-based UiO-66 MOF (UiO-66/SB-Pd) is synthesized through a straightforward post-modification process and utilized as a highly efficient catalyst in the Suzuki C-C coupling reaction. The designed UiO-66/SB-Pd material was characterized by using FT-IR, EDX, PXRD, TGA, N2 adsorption-desorption and SEM analyses. This catalyst displayed remarkable catalytic performance and stability in the Suzuki coupling reaction, facilitating the synthesis of a wide range of biaryl compounds. The catalyst retained its activity after seven consecutive cycles. Moreover, a leaching test indicated the excellent stability of the Pd active species under the reaction conditions.