Abstract
Two birds, one stone! The first kinetic resolution of allyl fluorides was achieved by the development of an organocatalyzed enantioselective allylic trifluoromethylation. Two kinds of chiral fluorinated compounds, which incorporate C-F and C-CF3 units, respectively, can thus be accessed by a single transformation. © 2014 WILEY-VCH Verlag GmbH.
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Nishimine, T., Fukushi, K., Shibata, N., Taira, H., Tokunaga, E., Yamano, A., … Shibata, N. (2014). Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted c-F bond cleavage. Angewandte Chemie - International Edition, 53(2), 517–520. https://doi.org/10.1002/anie.201308071
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