Use of CuO encapsulated in mesoporous silica SBA-15 as a recycled catalyst for allylic C-H bond oxidation of cyclic olefins at room temperature

Abstract

CuO nanoparticles were deposited on SBA-15 in three routes. These were metal loading on SBA-15 and calcination at 550 °C (Cu-SBA-15), metal loading on 3-aminopropyl-trimethoxysilane grafted SBA-15 and calcination at 550 °C (Cu-N-SBA-15), and metal loading on 3-aminopropyl-trimethoxysilane grafted SBA-15 and reduction by NaBH4 then calcination at 550 °C (Cu-B-N-SBA-15). These catalysts were characterized through powder X-ray diffraction (XRD), BET nitrogen adsorption-desorption methods, energy dispersive X-ray (EDX), atomic absorption spectroscopy (AAS), elemental mapping, scanning electron microscopy (SEM), and Fourier transform infrared (FT-IR) spectroscopy. The result of the heterogeneous catalysts being applied in the monometallic direct catalytic esterification of sp3 C-H bonds in cyclic olefins for the first time is reported, using tert-butyl 4-nitrobenzoperoxoate at room temperature. Allylic esters were obtained as the product of the C-H bond oxidation reaction in moderate to good yields (up to 99%) within reasonable reaction times. Also, the recovered catalyst (Cu-B-N-SBA-15) is applicable in the oxidation reaction for four times with little loss in reactivity and yield.