Lithium recovery from highly concentrated solutions: Response surface methodology (RSM) process parameters optimization

Abstract

Lithium recovery from aqueous solutions was studied by trapping lithium ions using a gel of aluminum hydroxide freshly prepared in situ under the reaction of a strong base. A 24 - 1 fractional factorial design and central composite design were employed for experimental design and analysis of the results. The combined effect of molar ratio Al/Li, pH and stirring time on lithium trapping at 25 °C was investigated and optimized using response surface methodology (RSM). The optimum values of these factors were found to be 4.7, 7.2 and 3 h respectively. In this case the lithium trapping percent is ∼ 95%. The obtained model is highly significant (Fobs > Ftabulate and low p-value) with a correlation coefficient of 96.64%. On the other hand, linear, quadratic and interaction terms in this model have the largest statistical effect on the response (confidence level = 99.9%). © 2007 Elsevier B.V. All rights reserved.