Error propagation in spectrometric functions of soil organic carbon

Abstract

Soil organic carbon (SOC) plays a major role concerning chemical, physical, and biological soil properties and functions. To get a better understanding of how soil management affects the SOC content, the precise monitoring of SOC on long-term field experiments (LTFEs) is needed. Visible and near-infrared (Vis NIR) reflectance spectrometry provides an inexpensive and fast opportunity to complement conventional SOC analysis and has often been used to predict SOC. For this study, 100 soil samples were collected at an LTFE in central Germany by two different sampling designs. SOC values ranged between 1.5% and 2.9 %. Regression models were built using partial least square regression (PLSR). In order to build robust models, a nested repeated 5-fold group cross-validation (CV) approach was used, which comprised model tuning and evaluation. Various aspects that influence the obtained error measure were analysed and discussed. Four pre-processing methods were compared in order to extract information regarding SOC from the spectra. Finally, the best model performance which did not consider error propagation corresponded to a mean RMSEMV of 0.12% SOC (R2 D 0:86). This model performance was impaired by 1RMSEMV D 0:04% SOC while considering input data uncertainties (1R2 D 0:09), and by 1RMSEMV D 0:12% SOC (1R2 D 0:17) considering an inappropriate pre-processing. The effect of the sampling design amounted to a 1RMSEMV of 0.02% SOC (1R2 D 0:05). Overall, we emphasize the necessity of transparent and precise documentation of the measurement protocol, the model building, and validation procedure in order to assess model performance in a comprehensive way and allow for a comparison between publications. The consideration of uncertainty propagation is essential when applying Vis-NIR spectrometry for soil monitoring.